UNITED STATES

SECURITIES AND EXCHANGE COMMISSION

WASHINGTON, DC 20549

FORM 8-K

CURRENT REPORT PURSUANT

TO SECTION 13 OR 15(D) OF THE

SECURITIES EXCHANGE ACT OF 1934

Date of report (Date of earliest event reported) June 12, 2007

THE PNC FINANCIAL SERVICES GROUP, INC.

(Exact Name of Registrant as Specified in Its Charter)

Pennsylvania

(State or Other Jurisdiction of Incorporation)

(412) 762-2000

(Registrant’s Telephone Number, Including Area Code)

(Former Name or Former Address, if Changed Since Last Report)

Check the appropriate box below if the Form 8-K filing is intended to simultaneously satisfy the filing obligation of the registrant under any of the following provisions (see General Instruction A.2. below):

On June 7, 2007, PNC Funding Corp (“Funding”), an indirect, wholly owned subsidiary of The PNC Financial Services Group, Inc. (the “Corporation”), completed the public offering of $500,000,000 aggregate principal amount of Floating Rate Senior Notes Due 2009 (the “Floating Rate Senior Notes”), pursuant to an Underwriting Agreement dated June 7, 2007 (the “Underwriting Agreement”) by and among Funding, the Corporation and Banc of America Securities LLC, as representative for several underwriters. The Underwriting Agreement is attached to this Current Report on Form 8-K as Exhibit 1.1. The Floating Rate Senior Notes were issued on June 12, 2007 pursuant to a Registration Statement on Form S-3 (Nos. 333-139912 and 333-139912-01), initially filed with the Securities and Exchange Commission (the “SEC”) on January 11, 2007 and effective immediately upon filing (the “Registration Statement”). A Preliminary Prospectus Supplement relating to the Floating Rate Senior Notes was filed with the SEC on June 7, 2007 pursuant to Rule 424(b) under the Securities Act. A free writing prospectus relating to the press release was filed with the SEC on June 7, 2007, pursuant to Rule 433 under the Securities Act of 1933, as amended (the “Securities Act”). A second free writing prospectus relating to the Floating Rate Senior Notes was filed with the SEC on June 8, 2007, pursuant to Rule 433 under the Securities Act. Lastly, a third free writing prospectus relating to the transcript of a conference call hosted by Friedman, Billings, Ramsey & Co., Inc. on June 7, 2007, with Richard J. Johnson, Chief Financial Officer of the Guarantor, was filed on June 8, 2007, pursuant to Rule 433 under the Securities Act. The form of the Floating Rate Senior Notes is attached to this Current Report on Form 8-K as Exhibit 4.1. The form of the related Guarantee for the Floating Rate Senior Notes is attached to this Current Report on Form 8-K as Exhibit 4.2.

This Current Report on Form 8-K is being filed for the purpose of filing the attached documents in connection with the issuance of the Floating Rate Senior Notes as exhibits to the Registration Statement and such exhibits are hereby incorporated by reference into the Registration Statement.

The following exhibits are filed herewith:

SIGNATURE

Pursuant to the requirements of the Securities Exchange Act of 1934, as amended, the registrant has duly caused this report to be signed on its behalf by the undersigned hereunto duly authorized.

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