Exhibit 23.2
Consent of Independent Registered Public Accounting Firm
We consent to the reference to our firm under the caption Experts in this Registration Statement
(Form S-4, No. 333-___) and related Proxy Statement/Prospectus of The PNC Financial Services
Group, Inc. for the registration of (a) 106,548,136 shares
of its common stock, (b) 1,500 shares of its 9.875%
Fixed-To-Floating Rate Non-Cumulative Preferred Stock, Series L,
and (c) 5,571 shares of its Non-Cumulative Perpetual
Preferred Stock, Series M, and to the
incorporation by reference of our reports dated February 13, 2008, with respect to the consolidated
financial statements of National City Corporation and the effectiveness of internal control over
financial reporting of National City Corporation, included in its Annual Report (Form 10-K) for the
year ended December 31, 2007, filed with the Securities and Exchange Commission.
/s/ Ernst & Young LLP
Cleveland, Ohio
November 6, 2008